The moment the PSU is plugged in and the main switch (if present) is on, the rail goes active. This powers:

Before the power button is even pressed, the motherboard must establish "always-on" voltages to monitor for a wake event. desktop motherboard power sequence pdf exclusive

Desktop Motherboard Power Sequence: Pdf Exclusive

The moment the PSU is plugged in and the main switch (if present) is on, the rail goes active. This powers:

Before the power button is even pressed, the motherboard must establish "always-on" voltages to monitor for a wake event.